Sasirangan is a traditional cloth of Banjar tribe of South Kalimantan. Sasirangan fabric is a type of fabric that is given a picture with the shades of the border-like stripes that extend from the bottom to the top (vertical). Staining of Sasirangan can be used from natural additive chemicals. There are six main colors of Sasirangan made from natural dyes additive chemicals found in South Kalimantan, namely: 1. Yellow from turmeric, 2. Red from gambier, noni fruit, red lombok, 3. Green, from pudak leaves or ginger, 4. Black from kabuau or uar, 5. Purple from seeds of gandaria (Ramania), and 6. Brown from uar or rambutan peel. In fact, Sasirangan can be used as a medium in instilling characters on learning in school. The characters that can be constructed through learning using natural substance chemicals substance on Sasirangan dying are: confidence, cultural, and economic value. Keywords—character value; dying; natural additive chemical; Sasirangan fabric