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Efficient hydrogenation of levulinic acid in water using a supported Ni–Sn alloy on aluminium hydroxide catalysts

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dc.creator Rudiansono, Rudiansono
dc.creator Maria, Dewi Astuti
dc.creator Takayoshi, Hara
dc.creator Nobuyuki , Ichikuni
dc.creator Shogo, Shimazu
dc.date 2015
dc.date.accessioned 2020-06-15T03:56:13Z
dc.date.available 2020-06-15T03:56:13Z
dc.identifier http://eprints.ulm.ac.id/903/1/Catalysis%20Science%20%26Technology%2C%202016%2C%20xx-xx.pdf
dc.identifier Rudiansono, Rudiansono and Maria, Dewi Astuti and Takayoshi, Hara and Nobuyuki , Ichikuni and Shogo, Shimazu (2015) Efficient hydrogenation of levulinic acid in water using a supported Ni–Sn alloy on aluminium hydroxide catalysts. View Article Online.
dc.identifier.uri https://repo-dosen.ulm.ac.id//handle/123456789/9080
dc.description Efficient hydrogenation of levulinic acid (LA) into γ-valerolactone (GVL) in water using highly dispersed Ni– SnIJx)/AlOH (x = Ni/Sn ratio) was studied. Increasing the Sn amount in the Ni–Sn alloy up to 2.14 mmol g−1 enhanced the yield of GVL, which slightly decreased when the Sn content was nearly 4 mmol g−1 (feeding Ni/Sn = 1.0). A stoichiometric amount of GVL (>99%) was achieved by using Ni–SnIJx)/AlOH (x = 3.0 and 1.4) at 393 K for 120 min in H2O. H2-treated Ni–SnIJ1.4)/AlOH consisting of Ni3Sn2 alloy species showed high selectivity towards GVL (>99% yield). The Ni–SnIJ1.4)/AlOH catalyst was reusable for at least six consecutive runs without any significant loss of activity and selectivity.
dc.format text
dc.relation http://eprints.ulm.ac.id/903/
dc.subject QD Chemistry
dc.title Efficient hydrogenation of levulinic acid in water using a supported Ni–Sn alloy on aluminium hydroxide catalysts
dc.type Article
dc.type PeerReviewed


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