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Highly efficient and selective hydrogenation of unsaturated carbonylcompounds using Ni–Sn alloy catalystsw

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dc.creator Rodiansono, Rodiansono
dc.creator Syahrul , Khairi
dc.creator Takayoshi, Hara
dc.creator Takayoshi, Ichikuni
dc.creator Shogo, Shimazu
dc.date 2012
dc.date.accessioned 2020-06-15T03:56:12Z
dc.date.available 2020-06-15T03:56:12Z
dc.identifier http://eprints.ulm.ac.id/902/1/Catal.%20Sci.%20T%20echnol.%2C%202012%2C%202%20%2C%202139%E2%80%932145.pdf
dc.identifier Rodiansono, Rodiansono and Syahrul , Khairi and Takayoshi, Hara and Takayoshi, Ichikuni and Shogo, Shimazu (2012) Highly efficient and selective hydrogenation of unsaturated carbonylcompounds using Ni–Sn alloy catalystsw. Catalysis Science & Technology (2). pp. 2139-2149.
dc.identifier.uri https://repo-dosen.ulm.ac.id//handle/123456789/9073
dc.description Inexpensive Ni–Sn-based alloy catalysts, both bulk and supported, exhibited high selectivity in the hydrogenation of a wide range of unsaturated carbonyl compounds and produced unsaturated alcohols almost exclusively. For the bulk Ni–Sn alloy catalysts, a relatively high reaction temperature of 453 K was required to achieve an efficient hydrogenation of CQO rather than CQC. The catalyst that consisted of the Ni–Sn alloy dispersed on TiO2 allowed a remarkable reduction of the reaction temperature to 383 K. Both the Ni3Sn2 and Ni3Sn alloy phases were found to be responsible for the enhancement of the chemoselectivity. The Ni–Sn alloy catalysts were reusable without any significant loss of selectivity
dc.format text
dc.relation http://eprints.ulm.ac.id/902/
dc.subject QD Chemistry
dc.title Highly efficient and selective hydrogenation of unsaturated carbonylcompounds using Ni–Sn alloy catalystsw
dc.type Article
dc.type PeerReviewed


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