| dc.creator |
Rudiansono, Rudiansono |
|
| dc.creator |
Maria, Dewi Astuti |
|
| dc.creator |
Syahrul , Khairi |
|
| dc.creator |
Shogo, Shimazu |
|
| dc.date |
2016 |
|
| dc.date.accessioned |
2020-06-15T03:56:12Z |
|
| dc.date.available |
2020-06-15T03:56:12Z |
|
| dc.identifier |
http://eprints.ulm.ac.id/901/1/Bulletin%20of%20Chemical%20Reaction%20Engineering%20%26%20Catalysis%2C%2011%20%281%29%2C%202016%2C%201-9.pdf |
|
| dc.identifier |
Rudiansono, Rudiansono and Maria, Dewi Astuti and Syahrul , Khairi and Shogo, Shimazu (2016) Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1). pp. 1-9. ISSN 1978-2993 |
|
| dc.identifier.uri |
https://repo-dosen.ulm.ac.id//handle/123456789/9067 |
|
| dc.description |
A highly active and selective hydrogenation of biomass-derived furfural into furfuryl alcohol was achieved using supported single phase Ni3Sn2 alloy catalysts. Various supports such as active carbon (AC), -Al2O3, Al(OH)3, ZnO, TiO2, ZrO2, MgO, Li-TN, and SiO2 have been employed in order to under-stand the role of the support on the formation of Ni3Sn2 alloy phase and its catalytic performance. Sup-ported Ni3Sn2 alloy catalysts were synthesised via a simple hydrothermal treatment of the mixture of aqueous solution of nickel chloride hexahydrate and ethanol solution of tin(II) chloride dihydrate in presence of ethylene glycol at 423 K for 24 h followed by H2 treatment at 673 K for 1.5 h, then charac-terised by using ICP-AES, XRD, H2- and N2-adsorption. XRD profiles of samples showed that the Ni3Sn2 alloy phases are readily formed during hydrothermal processes and become clearly observed at 2θ = 43-44o after H2 treatment. The presence of Ni3Sn2 alloy species that dispersed on the supports is believed to play a key role in highly active and selective hydrogenation of biomass-derived furfural to-wards furfuryl alcohol. Ni3Sn2 on TiO2 and ZnO supports exhibited much lower reaction temperature to achieved >99% yield of furfuryl alcohol product compared with other supports. The effects of loading amount of Ni-Sn, reaction conditions (temperature and time profile) on the activity and selectivity to-wards the desired product are systematically discussed. Copyright © 2016 BCREC GROUP. All rights reserved |
|
| dc.format |
text |
|
| dc.relation |
http://ejournal2.undip.ac.id/index.php/bcrec/article/view/393 |
|
| dc.relation |
http://eprints.ulm.ac.id/901/ |
|
| dc.subject |
QD Chemistry |
|
| dc.title |
Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports |
|
| dc.type |
Article |
|
| dc.type |
PeerReviewed |
|