Selective conversion of 2-methylfuran to 1,4-pentanediol catalyzed by bimetallic Ni-Sn alloy

Rodiansono; Astuti, Maria Dewi; Husain, Sadang; Nugroho, Agung; Sutomo

dc.contributor.author	Rodiansono
dc.contributor.author	Astuti, Maria Dewi
dc.contributor.author	Husain, Sadang
dc.contributor.author	Nugroho, Agung
dc.contributor.author	Sutomo
dc.date.accessioned	2021-09-02T03:45:44Z
dc.date.available	2021-09-02T03:45:44Z
dc.date.issued	2019-12
dc.identifier.issn	1978-2993
dc.identifier.uri	https://repo-dosen.ulm.ac.id//handle/123456789/21008
dc.description.abstract	The selective conversion of 2-methylfuran (2-MeF) to 1,4-pentanediol (1,4-PeD) over bimetallic nickel tin alloy catalysts in the ethanol/H2O solvent mixture was studied. By using bulk Ni-Sn(x); x = 3.0 and 1.5 catalysts, a maximum yield of 1,4-PeD (49%) was obtained at 94% conversion of 2-MeF. The dispersion of Ni-Sn(x) on the aluminium hydroxide (AlOH) or -Al2O3 supports allowed to an outstanding yield of 1,4-PeD (up to 64%) at 433 K, 3.0 MPa of H2 within 12 h. Ni-Sn(3.0)/AlOH catalyst was found to be reusable and the treatment of the recovered Ni-Sn(3.0)/AlOH catalyst with H2 at 673 K for 1 h restored the catalyst’s original activity and selectivity. Copyright © 2019 BCREC Group. All rights reserved	en_US
dc.language.iso	en	en_US
dc.publisher	Universitas Diponegoro Semarang	en_US
dc.relation.ispartofseries	Buletin of Chemical Reaction Engineering & Catalysis;Vol. 14 Issue 3
dc.subject	Ni-Sn alloy catalysts; selective conversion; 2-methylfuran; 1,4-pentanediol; 2- methyltetrahydrofuran	en_US
dc.title	Selective conversion of 2-methylfuran to 1,4-pentanediol catalyzed by bimetallic Ni-Sn alloy	en_US
dc.type	Article	en_US