| dc.creator |
Sutomo, Sutomo |
|
| dc.date |
2019-12 |
|
| dc.date.accessioned |
2020-06-15T04:04:47Z |
|
| dc.date.available |
2020-06-15T04:04:47Z |
|
| dc.identifier |
http://eprints.ulm.ac.id/8649/1/6.%20Journal_Sutomo_2019.pdf |
|
| dc.identifier |
Sutomo, Sutomo (2019) Selective Conversion of 2-Methylfuran to 1,4-Pentanediol Catalyzed by Bimetallic Ni-Sn Alloy. Selective Conversion of 2-Methylfuran to 1,4-Pentanediol Catalyzed by Bimetallic Ni-Sn Alloy, 14. ISSN e-ISSN 1978-2993 |
|
| dc.identifier.uri |
https://repo-dosen.ulm.ac.id//handle/123456789/13826 |
|
| dc.description |
The selective conversion of 2-methylfuran (2-MeF) to 1,4-pentanediol (1,4-PeD) over bimetallic nickel-tin alloy catalysts in the ethanol/H2O solvent mixture was studied. By using bulk Ni-Sn(x); x = 3.0 and 1.5 catalysts, a maximum yield of 1,4-PeD (49%) was obtained at 94% conversion of 2-MeF. The dispersion of Ni-Sn(x) on the aluminium hydroxide (AlOH) or -Al2O3supports allowed to an outstanding yield of 1,4-PeD (up to 64%) at 433 K, 3.0 MPa of H2within 12 h. Ni-Sn(3.0)/AlOH catalyst was found to be reusable and the treatment of the recovered Ni-Sn(3.0)/AlOH catalyst with H2at 673 K for 1 h restored the catalyst’s original activity and selectivity.Copyright © 2019 BCREC Group. All rights reservedKeywords: Ni-Sn alloy catalysts; selective conversion; 2-methylfuran; 1,4-pentanediol; 2-methyltetrahydrofuran |
|
| dc.format |
text |
|
| dc.publisher |
Bulletin of Chemical Reaction Engineering & Catalysis, , Schopus Q3; Sinta 1, |
|
| dc.relation |
http://eprints.ulm.ac.id/8649/ |
|
| dc.subject |
RS Pharmacy and materia medica |
|
| dc.title |
Selective Conversion of 2-Methylfuran to 1,4-Pentanediol Catalyzed by Bimetallic Ni-Sn Alloy |
|
| dc.type |
Article |
|
| dc.type |
PeerReviewed |
|